SBIR-STTR Award

Sn-SnSb Filled Carbon Fiber Anodes for High Energy Density Lithium Ion Batteries
Award last edited on: 3/22/2004

Sponsored Program
SBIR
Awarding Agency
NASA : JSC
Total Award Amount
$650,000
Award Phase
2
Solicitation Topic Code
-----

Principal Investigator
Fazlil Coowar

Company Information

Lithium Power Technologies Inc

20955 State Highway 6 Po Box 978
Manvel, TX 77578
   (281) 489-4889
   N/A
   www.lithiumpower.com
Location: Single
Congr. District: 22
County: Brazoria

Phase I

Contract Number: ----------
Start Date: ----    Completed: ----
Phase I year
2003
Phase I Amount
$75,000
An advanced material that exploits the excellent cycle life of a carbon fiber and the high gravimetric and volumetric capacity of the tin-based system is being proposed as a composite anode in lithium-ion batteries. Carbon fiber will be subjected to mild oxidation under oxygen so as to generate nano pores that will be subsequently filled by intermetallic materials SnSb using a sol-gel approach. The SnSb alloy in the porous carbon matrix is expected to be in the form of a nanofiber which is desirable for high rate capability and extended cycling. The carbon fiber will act not only as an electronic conductor but also as a cushion that will accommodate the volume changes during lithium intercalation and deintercalation. This composite anode when combined with a higher capacity cathode material LiCoxNiyAlzO2 should lead to energy density in excess of 230 Wh/Kg. These attributes of this proposed technology will definitely fulfill the battery requirements for space applications where cycle life of more than 30000 cycles for low earth orbit (LEO), high rate applications (> 4 kW/kg) and rapid charge/discharging (ten of seconds) and calendar life of more than 10 years for geosynchronous orbits (GEO) are needed. POTENTIAL COMMERCIAL APPLICATIONS The markedly higher performance values (energy density, reliability, weight, power, safety) combined with a markedly lower cost per unit of performance will energize a commercial market to drive these batteries into every civiil use where batteries goes today. Commercial markets extend to portable electronics, power tools, electric vehicles, and wearable computers, among others. We have also identified markets in the medical sector such as coclear implants and spinal cord stimulators.

Phase II

Contract Number: ----------
Start Date: ----    Completed: ----
Phase II year
2004
Phase II Amount
$575,000
___(NOTE: Note: no official Abstract exists of this Phase II projects. Abstract is modified by idi from relevant Phase I data. The specific Phase II work statement and objectives may differ)___ An advanced material that exploits the excellent cycle life of a carbon fiber and the high gravimetric and volumetric capacity of the tin-based system is being proposed as a composite anode in lithium-ion batteries. Carbon fiber will be subjected to mild oxidation under oxygen so as to generate nano pores that will be subsequently filled by intermetallic materials SnSb using a sol-gel approach. The SnSb alloy in the porous carbon matrix is expected to be in the form of a nanofiber which is desirable for high rate capability and extended cycling. The carbon fiber will act not only as an electronic conductor but also as a cushion that will accommodate the volume changes during lithium intercalation and deintercalation. This composite anode when combined with a higher capacity cathode material LiCoxNiyAlzO2 should lead to energy density in excess of 230 Wh/Kg. These attributes of this proposed technology will definitely fulfill the battery requirements for space applications where cycle life of more than 30000 cycles for low earth orbit (LEO), high rate applications (> 4 kW/kg) and rapid charge/discharging (ten of seconds) and calendar life of more than 10 years for geosynchronous orbits (GEO) are needed. POTENTIAL COMMERCIAL APPLICATIONS The markedly higher performance values (energy density, reliability, weight, power, safety) combined with a markedly lower cost per unit of performance will energize a commercial market to drive these batteries into every civiil use where batteries goes today. Commercial markets extend to portable electronics, power tools, electric vehicles, and wearable computers, among others. We have also identified markets in the medical sector such as coclear implants and spinal cord stimulators.