SBIR-STTR Award

Passivation of Indium-Phosphide Solar Cells
Award last edited on: 3/8/02

Sponsored Program
SBIR
Awarding Agency
NASA : LeRC
Total Award Amount
$669,186
Award Phase
2
Solicitation Topic Code
-----

Principal Investigator
Donald J Ciappenelli

Company Information

Gallia Inc

53 Beaver Road
Weston, MA 02493
   (617) 235-8726
   N/A
   N/A
Location: Single
Congr. District: 05
County: Middlesex

Phase I

Contract Number: ----------
Start Date: 00/00/00    Completed: 00/00/00
Phase I year
1993
Phase I Amount
$70,000
The high front surface recombination velocity (SRV) exhibited by indium phosphide (InP) solar cells has limited the level of efficiency that has been demonstrated to date. Gallia has developed metal organic chemical vapor deposition (MOCVD) methodology to enable the growth of a previously unknown wide band gap (4 eV) cubic-phase of gallium sulfide (GaS), which has been demonstrated to passivate III-V surfaces. Gallia's sulfide based coating will provide a proccessable method for the passivation of InP solar cell surfaces. The project objectives include: growth of high purity GaS films on InP, determination of the extent of surface passivation, fabrication and testing of GaS passivated InP solar cells, determination of GaS long term stability, and development of alternative III-VI passivation materials. Gallia will commit 900 man hours to these objectives. It is anticipated that the as a result of this program Gallia will be able to fabricate, by MOCVD, a series of gallium chalcogenide-based passivation coatings for InP solar cells. It is expected that the results of this project will benefit NASA in the possible fabrication of high efficiency InP solar cells for non-terrestrial applications.Upon the completion of Phase I NASA will have the potential of a new product, GaS passivated InP solar cell material, and a new process, passivation layers by MOCVD. The proposed project will have immediate and significant technological applications for the passivation of InP solar cell surfaces. Furthermore, the proposed project will serve as a model for passivation in the more general area of minority carrier devices.solar cell, Indium phosphide, Passivation, sulfidePhase 2 conversion

Phase II

Contract Number: ----------
Start Date: 00/00/00    Completed: 00/00/00
Phase II year
1994
Phase II Amount
$599,186
___(NOTE: Note: no official Abstract exists of this Phase II projects. Abstract is modified by idi from relevant Phase I data. The specific Phase II work statement and objectives may differ)___ The high front surface recombination velocity (SRV) exhibited by indium phosphide (InP) solar cells has limited the level of efficiency that has been demonstrated to date. Gallia has developed metal organic chemical vapor deposition (MOCVD) methodology to enable the growth of a previously unknown wide band gap (4 eV) cubic-phase of gallium sulfide (GaS), which has been demonstrated to passivate III-V surfaces. Gallia's sulfide based coating will provide a proccessable method for the passivation of InP solar cell surfaces. The project objectives include: growth of high purity GaS films on InP, determination of the extent of surface passivation, fabrication and testing of GaS passivated InP solar cells, determination of GaS long term stability, and development of alternative III-VI passivation materials. Gallia will commit 900 man hours to these objectives. It is anticipated that the as a result of this program Gallia will be able to fabricate, by MOCVD, a series of gallium chalcogenide-based passivation coatings for InP solar cells. It is expected that the results of this project will benefit NASA in the possible fabrication of high efficiency InP solar cells for non-terrestrial applications.Upon the completion of Phase I NASA will have the potential of a new product, GaS passivated InP solar cell material, and a new process, passivation layers by MOCVD. The proposed project will have immediate and significant technological applications for the passivation of InP solar cell surfaces. Furthermore, the proposed project will serve as a model for passivation in the more general area of minority carrier devices.solar cell, Indium phosphide, Passivation, sulfidePhase 2 conversion