SBIR-STTR Award

Abrasion-Resistant Membranes for Biomass Hydrolysate Clarification
Award last edited on: 11/9/2006

Sponsored Program
SBIR
Awarding Agency
DOE
Total Award Amount
$850,000
Award Phase
2
Solicitation Topic Code
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Principal Investigator
Paul Sheedy

Company Information

CeraMem Corporation

12 Clematis Avenue
Waltham, MA 02451
   (781) 899-4495
   N/A
   www.ceramem.com
Location: Multiple
Congr. District: 05
County: Middlesex

Phase I

Contract Number: ----------
Start Date: ----    Completed: ----
Phase I year
2005
Phase I Amount
$100,000
The conversion of lignocellulosic biomass to fuel ethanol is not yet economically competitive with the conversion of cornstarch to ethanol. The economics of lignocellulosic conversion could be improved if a wider range of high-value-added products could be produced by processing separate sugar streams. The separation of sugars from the hydrolysate mixture would involve advanced liquid-liquid separation processes. In order to minimize plugging and/or fouling of these advanced separation techniques, suspended solids in the hydrolysates produced from lignocellulosic biomass must be removed. Therefore, this project will develop corrosion and abrasion-resistant silicon carbide membranes for the separation of particulate and colloidal matter from hydrolysates generated during the processing of lignocellulosic biomass. In Phase I, laboratory-scale silicon carbide monoliths will be coated with a novel abrasion-resistant silicon carbide microfiltration membrane. The samples will be performance tested with biomass hydrolysate and then subjected to abrasion testing using a corundum suspension. Feasibility will be considered proven if the membrane shows high and stable process flux when processing hydrolysate and does not show any significant changes in process performance or microstructure after abrasion.

Commercial Applications and Other Benefits as described by the awardee:
Commercial applications for abrasion-resistant silicon carbide microfiltration membranes should include the clarification of lignocellulosic and cornstarch hydrolysate, raw sugar juice, and fuel ethanol stillage. The membranes should have longer useful lifetimes than other ceramic and polymeric membranes on the market and would be much less expensive than other inorganic membranes. These membranes should have a lower lifecycle cost than polymeric membranes used for these or similar applications

Phase II

Contract Number: ----------
Start Date: ----    Completed: ----
Phase II year
2006
Phase II Amount
$750,000
The development of processes to convert lignocellulosic biomass into ethanol and other chemicals is being enthusiastically pursued by the federal government as well as by private organizations. However, before these processes can be made cost effective, new materials are needed that are resistant to abrasion and corrosion in the aggressive streams associated with lignocellulosic processing - for example, in the removal of suspended solids from the hydrolysate produced in the pretreatment of biomass. This project will develop low-cost inorganic microfiltration membranes that have the requisite abrasion resistance and chemical durability for use in the clarification of hydrolysate generated during pretreatment. In Phase I, membrane fabrication and synthesis parameters were developed on laboratory-scale, ceramic membrane coupons. The performance of the new membrane was then demonstrated on a pretreated, corn stover hydrolysate sample. In Phase II, the membranes will be further optimized and scaled to produce pilot-scale elements. Field testing of the membrane elements will be conducted on hydrolysate streams.

Commercial Applications and Other Benefits as described by the awardee:
The new membranes should find use in the separation and isolation of the sugars produced during the hydrolysis of lignocellulosic biomass. If chemicals can be produced from biomass sugars, the process of converting biomass to ethanol would become more cost effective, providing Americans with an abundant supply of fuel and reducing the need to import petroleum. Other applications of the membrane technology include clarification processes in the production of sweeteners, sugars, and fruit juices