SBIR-STTR Award

A novel concept for efficient production of liquid fuels from coal using flash pyrolysis in vibrated fluidized beds
Award last edited on: 9/9/2002

Sponsored Program
SBIR
Awarding Agency
DOE
Total Award Amount
$550,000
Award Phase
2
Solicitation Topic Code
-----

Principal Investigator
Arthur P Fraas

Company Information

PAI Corporation

116 Milan Way
Oak Ridge, TN 37830
   (865) 483-0666
   david.rhodes@paicorp.com
   www.paicorp.com
Location: Single
Congr. District: 03
County: Anderson

Phase I

Contract Number: N/A
Start Date: 00/00/00    Completed: 00/00/00
Phase I year
1988
Phase I Amount
$50,000
In spite of major efforts to develop processes for converting coal into liquid hydrocarbons for motor fuel, none has attained commercial viability because of difficulties with poor conversion efficiencies and high capital costs. This project is based on the coupling of flash pyrolysis with new advances in vibrated fluidized beds and promises to reduce coal-particle dwell time and the time to quench the products by at least an order of magnitude, thus drastically reducing polymerization of the products. The novel design for the skimming flash pyrolyzer is an add-on system to preheat the coal en route to the furnace of the power plant. In this way, the coal utilization is up to 90% (as compared to about 50% for current coal liquefaction processes), the system capital cost is greatly reduced, and environmental impacts of the overall coal utilization are minimized. A side stream of 900ø C lime-ash-char mixture from the top of a fluidized-bed coal furnace will be diverted to a non-oxidizing vibratory pyrolyzer into which a stream of crushed coal is fed. The feed rates for the two streams will be adjusted to give a mixture temperature of about 550ø C. The bed thickness (about 2 to 3 cm) and the vibration frequencies (about 25 to 100 Hz) will be adjusted so that the particles will dwell in the pyrolyzer for only a few seconds before leaving for the furnace. The light hydrocarbons evolved will not have to be sent through a cyclone separator but can be directly quenched by a tube bank placed close to the bed. Phase I will be directed at a critical evaluation of the concept, with particular attention to the effects of transit times on reducing objectionable polymerization of the evolved gases and vapor. Phase II will be directed at determining key parameters in a laboratory-scale experiment. The application of the concept to oil shale retorting will also be examined.Anticipated Results/Potential Commercial Applications as described by the awardee: A breakthrough in the efficient and cost-effective liquefaction of coal and retorting of oil shale would bring large economic benefits to the United States. The proposed concept has the potential to add to every new 600 MWe coalfired steam-electric plant a 2000 bbl/d oil producer that has the same capacity factor as the plant (e.g., about 75%), and that has the advantages of increasing the economic utilization and reducing the waste disposal problems associated with a national coal utilization policy.Topic 20: Coal Utilation and Conservation

Phase II

Contract Number: N/A
Start Date: 00/00/00    Completed: 00/00/00
Phase II year
1989
Phase II Amount
$500,000
___(NOTE: Note: no official Abstract exists of this Phase II projects. Abstract is modified by idi from relevant Phase I data. The specific Phase II work statement and objectives may differ)___ In spite of major efforts to develop processes for converting coal into liquid hydrocarbons for motor fuel, none has attained commercial viability because of difficulties with poor conversion efficiencies and high capital costs. This project is based on the coupling of flash pyrolysis with new advances in vibrated fluidized beds and promises to reduce coal-particle dwell time and the time to quench the products by at least an order of magnitude, thus drastically reducing polymerization of the products. The novel design for the skimming flash pyrolyzer is an add-on system to preheat the coal en route to the furnace of the power plant. In this way, the coal utilization is up to 90% (as compared to about 50% for current coal liquefaction processes), the system capital cost is greatly reduced, and environmental impacts of the overall coal utilization are minimized. A side stream of 900ø C lime-ash-char mixture from the top of a fluidized-bed coal furnace will be diverted to a non-oxidizing vibratory pyrolyzer into which a stream of crushed coal is fed. The feed rates for the two streams will be adjusted to give a mixture temperature of about 550ø C. The bed thickness (about 2 to 3 cm) and the vibration frequencies (about 25 to 100 Hz) will be adjusted so that the particles will dwell in the pyrolyzer for only a few seconds before leaving for the furnace. The light hydrocarbons evolved will not have to be sent through a cyclone separator but can be directly quenched by a tube bank placed close to the bed. Phase I will be directed at a critical evaluation of the concept, with particular attention to the effects of transit times on reducing objectionable polymerization of the evolved gases and vapor. Phase II will be directed at determining key parameters in a laboratory-scale experiment. The application of the concept to oil shale retorting will also be examined.Anticipated Results/Potential Commercial Applications as described by the awardee: A breakthrough in the efficient and cost-effective liquefaction of coal and retorting of oil shale would bring large economic benefits to the United States. The proposed concept has the potential to add to every new 600 MWe coalfired steam-electric plant a 2000 bbl/d oil producer that has the same capacity factor as the plant (e.g., about 75%), and that has the advantages of increasing the economic utilization and reducing the waste disposal problems associated with a national coal utilization policy.Topic 20: Coal Utilation and Conservation