SBIR-STTR Award

Tib2 reinforced intermetallic matrix composite
Award last edited on: 3/13/02

Sponsored Program
SBIR
Awarding Agency
DOD : DARPA
Total Award Amount
$295,599
Award Phase
2
Solicitation Topic Code
SB891-033
Principal Investigator
Ranjan Ray

Company Information

Marko Materials Inc

19-1 Sterling Road PO Box 3
North Billerica, MA 01862
   (508) 663-2210
   N/A
   N/A
Location: Single
Congr. District: 06
County: Middlesex

Phase I

Contract Number: DAAH0189C0723
Start Date: 8/8/89    Completed: 00/00/00
Phase I year
1989
Phase I Amount
$50,000
Development of suitable reinforcement fibers for high temperature composite Materials is the Major technical barrier limiting the introduction of these new Materials for advanced aircraft engines. We propose to fabricate monofilament tib(2) fibers using a novel concept. The choice of tib(2) fibers is based on its chemical com patibility with aluminide Matrices, higher coefficients of thermal expansion and elastic modulus, and lower density compared to other candidate reinforcement fibers. In the first step of the proposed novel fabrication technique, we will obtain a b rich ti filament directly from the melt using an advanced melt spinning technique. In the second step the b rich ti filament will be coated with lowcost b coatings using an innovative chemical vapor deposition (cvd) process that combines the low cost of pack metallization with the high heat and Mass transfer of a fluidized bed reactor. We will characterize the mechanical and microstructural properties of the tib(2) fibers fabricated using the above technique, giving particular attention to the extent of degree of diffusion and reaction between the b rich ti substrate and b coating. The low cost b coatings via cvd in a fluidized bed reactor will be performed in collaboration with drs. Angel san jurjo and digby Macdonald of sri international, Menlo Park, CA.

Phase II

Contract Number: DAAH01-91-C-R153
Start Date: 00/00/00    Completed: 00/00/00
Phase II year
1991
Phase II Amount
$245,599
Development of suitable continuous reinforcement fibers for high temperature composite materials is the major technical barrier limiting the introduction of these new materials for advanced aircraft engines. During DARPA SBIR Phase I program we demonstrated the technical feasibility of a manufacturing process for TIB2 ribbon via a novel route which combined an advanced melt spinning process and chemical vapor deposition. Under the proposed Phase II program we intend to develop techniques for fabrication of continuous wide ribbons of niobium alloys by the melt spinning technique. The niobium ribbons will be subsequently coated with TIB2 by a CVD technique. TIB2 ribbons with niobium core will be utilized as reinforcing elements to fabricate Intermetallic Matrix Composites (IMC) using the powder materials processing route. Various intermetallic compositions based on aluminides and silicides of titanium, nickel, niobium and molybdenum will be screened as potential matrices for reinforcement with TIB2. A major task of Phase II program will be to characterize the microstructures and preliminary mechanical properties of the TIB2 reinforced IMC. Anticipated Benefits/Potential Commercial Applications - High modulus TIB2 ribbons reinforced Intermetallic Matrix Composites will find applications in advanced gas turbine engines and advanced propulsion systems for transatmospheric flight vehicles operating at 2000-3000F degrees. Commercial applications will be in future (21st century) civil propulsion systems with greatly increased fuel economy improved reliability, extended life and reduced operating costs.