SBIR-STTR Award

Commercial Applications for Recycled Rare Earth Zirconate Thermal Barrier Coating Materials
Award last edited on: 6/11/2021

Sponsored Program
SBIR
Awarding Agency
DOD : DLA
Total Award Amount
$1,099,304
Award Phase
2
Solicitation Topic Code
DLA202-009
Principal Investigator
Nicholas Burlingame

Company Information

Xylon Technical Ceramics Inc

200 North Main Street
Alfred, NY 14802
   (607) 382-2559
   N/A
   N/A
Location: Single
Congr. District: 23
County: Allegany

Phase I

Contract Number: SP4701-21-P-0026
Start Date: 12/2/2020    Completed: 6/1/2021
Phase I year
2021
Phase I Amount
$99,965
This Phase I project seeks to develop a method for the recycling of rare earth zirconate thermal barrier coatings (TBCs). Thermal barrier coatings are crucial to the function and performance of military aircraft engines, as they influence the operating temperatures and environments for the aircrafts. There are currently two main types of established thermal barrier coating materials, yttria-stabilized zirconia (YSZ) and gadolinium zirconate (Gd2Zr2O7). These two coatings materials have been carefully developed and extensively tested for use in both commercial and military applications. Since these thermal barrier coating materials have become firmly entrenched in the aviation defense supply chain, it is imperative that the methods and materials used in producing these coatings are maintained. However, the production sources of the rare earth and zirconia raw materials necessary for the manufacture of these coatings are concentrated almost entirely in China. The limited supply options for the TBC raw materials results in substantial uncertainty regarding the availability of these materials for use in TBCs. Xylon Technical Ceramics has developed and patented a novel, environmentally friendly technology that is capable of recycling rare earth zirconate wastes into their core chemical components at high purities. Xylon plans to utilize this process to recycle gadolinium oxide from Gd2Zr2O7 wastes directly back into current commercial thermal barrier coating operations, thereby creating a domestic source of these critical raw materials to benefit military and commercial users.

Phase II

Contract Number: SP4701-22-C-0009
Start Date: 11/9/2021    Completed: 5/8/2023
Phase II year
2022
Phase II Amount
$999,339
This Phase II project seeks to develop a method for the recycling of rare earth zirconate thermal barrier coatings (TBCs). Thermal barrier coatings are crucial to the function and performance of military aircraft engines, as they influence the operating temperatures and environments for the aircrafts. There are currently two main types of established thermal barrier coating materials, yttria-stabilized zirconia (YSZ) and gadolinium zirconate (Gd2Zr2O7). These two coatings materials have been carefully developed and extensively tested for use in both commercial and military applications. Since these thermal barrier coating materials have become firmly entrenched in the aviation defense supply chain, it is imperative that the methods and materials used in producing these coatings are maintained. However, the production sources of the rare earth and zirconia raw materials necessary for the manufacture of these coatings are concentrated almost entirely in China. The limited supply options for the TBC raw materials results in substantial uncertainty regarding the availability of these materials for use in TBCs. Xylon Technical Ceramics has developed and patented a novel, environmentally friendly technology that is capable of recycling rare earth zirconate wastes into their core chemical components at high purities. Xylon plans to utilize this process to recycle gadolinium oxide from Gd2Zr2O7 and other TBC wastes directly back into current commercial thermal barrier coating operations, thereby creating a domestic source of these critical raw materials to benefit military and commercial users.