SBIR-STTR Award

Isocyanate-Free Polyurethane Resins for One-Component, Ambient-Cure Coatings
Award last edited on: 3/9/2024

Sponsored Program
SBIR
Awarding Agency
EPA
Total Award Amount
$400,000
Award Phase
2
Solicitation Topic Code
15-NCER-04
Principal Investigator
Bret J Chisholm

Company Information

Renuvix

1854 NDSU Research Circle N
Fargo, ND 58102
   (701) 388-1997
   N/A
   www.renuvix.com
Location: Single
Congr. District: 00
County: Cass

Phase I

Contract Number: EPD17005
Start Date: 11/1/2016    Completed: 4/30/2017
Phase I year
2016
Phase I Amount
$100,000
Due to their exceptional properties, polyurethane coatings are used extensively in our society. Unfortunately, the socyanate-functional components used in the curing of polyurethanes are generally toxic. Thus, there is a need for polyurethane resins that can be cured without the use of isocyanate-functional components. In addition to enabling the production of polyurethane coatings that are free of isocyanate groups, the proposed resin technology will also provide several other benefits to the coating formulator as well as the coating end-user. A major benefit includes the ability to produce one-component, ambient-cure coatings from the resins. One-component, ambient-cure coatings are highly desired because they are applicator friendly, low in waste generation, and they eliminate energy costs associated with the curing process. The polyurethane resins that can be produced with the proposed technology are also expected to provide several property enhancements over the current state-of-the-art in one-component, ambient-cure coating resins. These enhancements include short drying/curing times, exceptional hardness and solvent/chemical resistance, and the potential for producing coatings that have little to no emissions of organic pollutants. Furthermore, the proposed resin technology utilizes components derived from renewable resources, which is better for the environment and reduces dependence on fossil resources.

Phase II

Contract Number: EPD18006
Start Date: 2/1/2018    Completed: 3/13/2018
Phase II year
2017
Phase II Amount
$300,000
The Phase I project showed that novel urethane-functional (NUF) resins could be produced that were free of isocyanates and very useful for one-component, ambient-cured (OCAC) coatings. Resins for OCAC coatings, which are expected to be valued at $5.7 billion by 2019, are used to produce a variety of coatings including oil-based paints, wood stains, varnishes, and aerosol paints. Phase I results showed that NUF resins could be used to overcome a major limitation associated with the current state-of-the-art for OCAC coating resins. This limitation is the ability to significantly reduce the level of solvent in the coating without sacrificing coating performance characteristics, such as drying/curing time, durability/hardness, and chemical resistance. Thus, NUF resins provide high performance OCAC coatings with substantially lower levels of air pollutants (i.e. solvents). An added environmental benefit associated with NUF resins are their ultra-high biobased content. Coatings with a high biobased content are better for the environment and reduce our Nation's dependence on fossil resources. In addition, coating resins with a high biobased content enable product preference incentives for the coating supplier or coating end-user. Results from the Phase I project were shared with multiple potential customers and their support for further development received.